Rapid
Microwave-Solvothermal Synthesis and Surface Modification of
Nanostructured Phospho-olivine Cathodes for Lithium Ion Batteries
Description
Lithium ion batteries currently use layered LiCoO2 as a cathode
material, but cobalt is relatively expensive and toxic. The
high cost of cobalt is preventing the development of the lithium
ion battery technology for hybrid and electric vehicle applications.
In this regard, LiFePO4 crystallizing in the olivine structure
has become appealing, as iron is inexpensive and environmentally
benign. However, LiFePO4 has to be synthesized as a nanomaterial
to decrease the lithium diffusion length, and the grains must
be decorated with conductive carbon to increase the electronic
conductivity.
Current methods employed to achieve acceptable electronic
and lithium ion conductivities are expensive and time-consuming,
involving multiple steps and annealing in reduced atmospheric
environments. The novel method developed at UT is capable
of obtaining well-defined nanostructured LiFePO4 powder within
15 minutes, with high crystallinity at low temperatures without
any further heat treatment required.
Inventors at The University of Texas at Austin have created
a novel method for manufacturing LiFePO4 for use in cathodes
to create lithium ion batteries. By adopting this novel process,
the investigators have shown the ability to synthesize pristine
LiFePO4, thereby improving manufacturing cleanliness, shortening
reaction times, and increasing energy savings. This method
offers small nano-sized LiFePO4 particles with a uniform size
distribution and high crystallinity.
Benefits
- Low manufacturing cost
- Reduced time to manufacture
Market Potential/Applications
This novel method offers a cost-effective route to manufacture
the lithium iron phosphate cathodes in a reliable and consistent
manner for high power lithium ion batteries that are of interest
for power tool, hybrid electric vehicles, and plug-in electric
vehicles applications.
Contact:
University of Texas,
Austin, USA
Website : www.otc.utexas.edu

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