| Enzymatic
Processing of Leather
Introduction
Environmental pollution caused by different effluents generated
during the processing/ manufacturing of leather is one of
the serious problems the country is facing today. Due to the
violation of pollution control norms set by the Indian Government,
some of the tanneries are forced to close down rendering people
jobless and resulting in the loss of valuable foreign exchange
to the country. Biotechnology, particularly the use of enzymes
offer an opportunity to add value by providing improved cleaner
processes for leather production and enhanced environmental
management in the industry.
Currently, the most commonly used biotechnology applications
cover all the stages of leather making processes and treatment
of waste. An emerging technology is the use of proteolytic
enzymes in unhairing process, which minimizes/replaces the
use of sulphide, a major pollutant in the tannery.
In search of an eco-friendly, cost effective depilant for
the unhairing process alkaline proteases was produced by isolating
some microbes Aspergillus species from the local soil of IIT-Kharagpur
has been evaluated for its efficacy. The activity and the
performance of the enzyme have satisfied the conditions necessary
for its application as depilant. The physical testing data
(tensile strength, percent elongation and tearing strength)
of the skins unhaired by enzymatic and chemical treatments
were compared to evaluate the strength properties of the leather.
The enzymatically treated leather was found to be superior
to the leather obtained through chemical treatment. The comparison
of microscopical structure of enzyme treated and lime sulphide
treated pelts showed that the enzyme removes the intact hair
which can be collected and used further.
| Sl. No |
Sample |
Tensile strength
(kg/cm 2 ) |
Elongation (%) |
Tearing strength
(kg/cm) |
| 1 |
Lime sulphide goat (belly)
|
413.10 |
32.37 |
43.00 |
| 2 |
Enzyme treated goat
(belly) |
621.18 |
42.10 |
65.00 |
| 3 |
Lime sulphide goat (back
bone) |
335.58 |
3.87 |
34.00 |
| 4 |
Enzyme treated goat
(back bone) |
428.40 |
64.363 |
58.00 |
These results prove that enzymatic unhairing
can be an excellent alternative to the age old chemical process
as the trend is more towards cleaner technology and eco-friendly
environment.
At IIT Kharagpur semi-pilot scale production and the application
of the enzyme have been successfully carried out on different
types of pelt. The process is found to be techno-economically
viable one and the salient features of the indigenously developed
product are given below.
Product Description:
- By enzymatic unhairing process, sulphide can be replaced
totally, which are toxic in nature.
- No health hazard, worker can use this enzyme even in bare
hand.
- Produced improved quality leather.
- % elongation, tensile strength, stitch tear strength also
improves.
- For the manufacture of leather, unhairing is the first
and most important step.
- Till date the conventional practice is to use sodium sulphide
as depilatory agent.
- Among the disadvantages of the use of these chemicals
is environmental pollution, health hazard.
- Enzymatic process of unhairing is considered to be the
best and efficient alternative to the conventional lime-sulphide
method.
Salient Features:
- Eco-friendly process
- Additional leather area (5%-10%)
- Cost saving on sulphide
- Hair recovery from goat and sheep skin
- Work in room temperature condition
- Required less amount of water during washing step so dispose
of waste water
- problem also solved
- Giving better result under drumming
- Residual biomass after enzyme extraction can be used for
biofuel production
- Unhairing could be accomplished in 5-7 hrs
- Better quality leather fetching higher price
| Suggested
minimum plant capacity: 300 MT per annum |
| Likely
investment: ~ Rs.1.5
Crores |
| Production
cost using Enzyme: ~ Rs 30-40/kg (Compared to conventional
production cost: Rs.34/kg using sulphide (Rs.28/kg) &
lime (Rs.6.00/kg) |
| Indian Patent has been
obtained on this technology. |
Contact for more information:
Prof. R. Banerjee
Microbial Biotechnology & Downstream Processing Laboratory
Agricultural & Food Engineering Department
Indian Institute of Technology
Kharagpur - 721 302
Phone Number: +91-3222-283104(O)/283105(R)
Email: rb@iitkgp.ac.in
,rin_tuin@yahoo.com

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